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Author:

Cao, Lin-Hong (Cao, Lin-Hong.) | Wu, Wei-Dong (Wu, Wei-Dong.) | Zhang, Zhen (Zhang, Zhen.) | Xu, Zhuo (Xu, Zhuo.) | Xu, Guang-Liang (Xu, Guang-Liang.)

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Scopus CSCD PKU SCOPUS

Abstract:

Using SrCO3 and TiO2 as raw materials, the tabular intermediates Sr3Ti2O7 was synthesized by molten salt method. The phase composition and microstructure of these powders were analyzed by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The effects of molten salt (NaCl and KC1), reactive temperature and reactive time on the synthesis of tabular intermediates Sr3Ti2O7 were discussed in this paper. The results showed that the intermediates obtained by using KC1 as molten salt were composed of anisotropic Sr3Ti2O7 and Sr2 TiO4. The intermediates obtained by using NaCl as molten salt were composed of anisotropic Sr3Ti2O7, Sr2 TiO4 and Sr4Ti3O10. There have little effect on phase composition and phase contents by using excessive SrCO3 or improving synthesis temperature. Moreover, by using excessive SrCO3 or improving synthesis temperature, the contents of Sr3Ti2O7 increase, but that of Sr2TiO4 decreases. The intermediates obtained at 1300°C for 4 h by using NaCl as molten salt were rectangle and tabular, its edge length and thickness is 30-60 μm and 2-5 μm respectively, which is the idea template for epitaxial growth of <001>SrTiO3 tabular crystals. However, the intermediates obtained by using KCl as molten salt were also rectangle and tabular, its edge length and thickness is 10-20 μm and 5-10 μm.

Keyword:

Microstructure Molten salt method Tabular Sr3Ti2O7 XRD

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Source :

Yadian Yu Shengguang/Piezoelectrics and Acoustooptics

ISSN: 1004-2474

Year: 2009

Issue: 3

Volume: 31

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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