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Abstract:
It is well known that first-order ferroelectric to paraelectric transition is a one-step transition and it gives rise to one latent heat peak and one permittivity peak during heating. In the present paper, however, we report an unexpected finding; in Mn-doped Ba(Zr(0.01)Ti(0.98)Mn(0.01))O(3-delta) the ferroelectric to paraelectric transition proceeds in two steps, after the sample has experienced a prior aging at the differential scanning calorimetry (DSC) peak temperature and followed by cooling down to a fully ferroelectric state. The two-step transition is evidenced by a split DSC peak as well as a split permittivity peak. These abnormal effects can be explained by considering that aging at DSC peak temperature corresponds to aging in a two-phase state (paraelectric+ferroelectric). Such two-phase aging produces two different defect symmetries, which give rise to different stabilities for the same ferroelectric phase and thus results in different reverse transition temperatures.
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APPLIED PHYSICS LETTERS
ISSN: 0003-6951
Year: 2010
Issue: 8
Volume: 96
3 . 8 4 1
JCR@2010
3 . 7 9 1
JCR@2020
ESI Discipline: PHYSICS;
JCR Journal Grade:1
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 9
SCOPUS Cited Count: 15
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4