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Author:

Gao, Jinghui (Gao, Jinghui.) | Xue, Dezhen (Xue, Dezhen.) | Bao, Huixin (Bao, Huixin.) | Zhang, Lixue (Zhang, Lixue.) | Zhou, Chao (Zhou, Chao.) | Liu, Wenfeng (Liu, Wenfeng.) (Scholars:刘文凤) | Chen, Wei (Chen, Wei.) | Ren, Xiaobing (Ren, Xiaobing.) (Scholars:任晓兵)

Indexed by:

SCIE EI Scopus

Abstract:

It is well known that first-order ferroelectric to paraelectric transition is a one-step transition and it gives rise to one latent heat peak and one permittivity peak during heating. In the present paper, however, we report an unexpected finding; in Mn-doped Ba(Zr(0.01)Ti(0.98)Mn(0.01))O(3-delta) the ferroelectric to paraelectric transition proceeds in two steps, after the sample has experienced a prior aging at the differential scanning calorimetry (DSC) peak temperature and followed by cooling down to a fully ferroelectric state. The two-step transition is evidenced by a split DSC peak as well as a split permittivity peak. These abnormal effects can be explained by considering that aging at DSC peak temperature corresponds to aging in a two-phase state (paraelectric+ferroelectric). Such two-phase aging produces two different defect symmetries, which give rise to different stabilities for the same ferroelectric phase and thus results in different reverse transition temperatures.

Keyword:

ageing barium compounds defect states differential scanning calorimetry ferroelectric materials ferroelectric transitions latent heat manganese permittivity zirconium compounds

Author Community:

  • [ 1 ] [Gao, Jinghui; Xue, Dezhen; Bao, Huixin; Zhang, Lixue; Zhou, Chao; Liu, Wenfeng; Chen, Wei; Ren, Xiaobing] Xi An Jiao Tong Univ, Multidisciplinary Mat Res Ctr, Xian 710049, Peoples R China
  • [ 2 ] [Gao, Jinghui; Zhou, Chao; Liu, Wenfeng; Chen, Wei] Xi An Jiao Tong Univ, State Key Lab Elect Insulat & Power Equipment, Xian 710049, Peoples R China
  • [ 3 ] [Gao, Jinghui; Xue, Dezhen; Bao, Huixin; Zhou, Chao; Ren, Xiaobing] Natl Inst Mat Sci, Ferro Phys Grp, Tsukuba, Ibaraki 3050047, Japan

Reprint Author's Address:

  • 任晓兵

    Xi An Jiao Tong Univ, Multidisciplinary Mat Res Ctr, Xian 710049, Peoples R China.

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Source :

APPLIED PHYSICS LETTERS

ISSN: 0003-6951

Year: 2010

Issue: 8

Volume: 96

3 . 8 4 1

JCR@2010

3 . 7 9 1

JCR@2020

ESI Discipline: PHYSICS;

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 9

SCOPUS Cited Count: 15

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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