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Author:

Wu, Guizhi (Wu, Guizhi.) | Ma, Shengli (Ma, Shengli.) | Xu, Kewei (Xu, Kewei.) | Ji, Vincent (Ji, Vincent.) | Chu, Paul K. (Chu, Paul K..)

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Abstract:

The oxidation behavior of Ti-Al-Si-C-N hard coatings with different Al contents deposited on highspeed steel and Si substrates by hybrid arc-enhanced magnetron sputtering is investigated in the temperature range of 500 degrees C-1000 degrees C. The coating hardness is maintained at around 35 GPa, and the parabolic oxidation rate constant K-p at 1000 degrees C decreases to 3.36 x 10(-10) kg(2) m(-4) s(-1) when the Al concentration is increased to 30 at. %, indicating that Ti-Al-Si-C-N coatings with larger Al concentrations have better oxidation resistance. X-ray diffraction, cross-sectional scanning electron microscopy, and x-ray photoelectron spectroscopy reveal a protective surface layer consisting of Al2O3, TiO2, and SiO2 that retards inward oxygen diffusion. A mechanism is proposed to elucidate the oxide formation. As a consequence of the good oxidation resistance, the Ti-Al-Si-C-N coatings have a large potential in high-speed dry cutting as well as other high temperature applications. (C) 2012 American Vacuum Society. [http://dx.doi.org/10.1116/1.4721376]

Keyword:

Author Community:

  • [ 1 ] [Wu, Guizhi; Ma, Shengli; Xu, Kewei] Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
  • [ 2 ] [Ji, Vincent] Univ Paris 11, ICMMO LEMHE, F-91405 Orsay, France
  • [ 3 ] [Chu, Paul K.] City Univ Hong Kong, Dept Phys & Mat Sci, Kowloon, Hong Kong, Peoples R China

Reprint Author's Address:

  • Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China.

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Source :

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A

ISSN: 0734-2101

Year: 2012

Issue: 4

Volume: 30

1 . 4 3 2

JCR@2012

2 . 4 2 7

JCR@2020

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:325

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 3

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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