In　this　work,　expanded　MoS2　nanosheets　grown　on　nitrogen-doped　branched　TiO2/C　nanofibers　(NBT/C@MoS2　NFs)　are　prepared　through　electrospinning　and　hydrothermal　treatment　method　as　anode　materials　for　sodium-ion　batteries　(SIBs).　The　continuous　1D　branched　TiO2/C　nanofibers　provide　a　large　surface　area　to　grow　expanded　MoS2　nanosheets　and　enhance　the　electronic　conductivity　and　cycling　stability　of　the　electrode.　The　large　surface　area　and　doping　of　nitrogen　can　facilitate　the　transfer　of　both　Na+　ions　and　electrons.　With　the　merits　of　these　unique　design　and　extrinsic　pseudocapacitance　behavior,　the　NBT/C@MoS2　NFs　can　deliver　ultralong　cycle　stability　of　448.2　mA　h　g(-1)　at　200　mA　g(-1)　after　600　cycles.　Even　at　a　high　rate　of　2000　mA　g(-1),　a　reversible　capacity　of　258.3　mA　h　g(-1)　can　still　be　achieved.　The　kinetic　analysis　demonstrates　that　pseudocapacitive　contribution　is　the　major　factor　to　achieve　excellent　rate　performance.　The　rational　design　and　excellent　electrochemical　performance　endow　the　NBT/C@MoS2　NFs　with　potentials　as　promising　anode　materials　for　SIBs.