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Polypropylene has great potential as a thermoplastic insulation material for high voltage direct current (HVDC) cable. However, its mechanical properties restrict its application, particularly at low temperature. In this paper, isotactic polypropylene (iPP) with the β-nucleating agent WBG was prepared by the melt blending method. The crystallinity, β-crystal proportion and crystalline morphology were analyzed by wide-angle X-ray diffraction, differential scanning calorimetry, scanning electron microscopy and polarized optical microscopy. The results showed that the crystallinity and β-crystal proportion increased as the WBG concentration increased. Three types of β-crystal morphology, namely β-spherulite, flower-like agglomerate and β-quasi-spherulite, were sequentially obtained with increasing WBG concentration. The mechanical properties, space charge distribution, thermally stimulated discharge current and DC electrical breakdown strength were investigated. Compared with pure iPP, the Izod impact strength and DC breakdown strength of iPP/0.1%WBG were improved by 238 and 16%, respectively, and the fracture energy and brittleness temperature of iPP/0.3%WBG were improved by 420 and 80%, respectively. In addition, the space charge accumulation was suppressed in the range of 0.1-0.5 wt% WBG. Chain coupling between the β-crystals and the amorphous phase, particularly in the flower-like agglomerates, was considered to play an important role in improving the mechanical and electrical performance. © 2019 IEEE.
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IEEE Transactions on Dielectrics and Electrical Insulation
ISSN: 1070-9878
Year: 2019
Issue: 3
Volume: 26
Page: 714-721
2 . 5 5 4
JCR@2019
2 . 9 3 1
JCR@2020
ESI Discipline: ENGINEERING;
ESI HC Threshold:83
JCR Journal Grade:2
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 0
SCOPUS Cited Count: 46
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 11
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