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Author:

Zhao, Yinchao (Zhao, Yinchao.) | Liu, Chenguang (Liu, Chenguang.) | Sun, Yi (Sun, Yi.) | Yi, Ruowei (Yi, Ruowei.) | Cai, Yutao (Cai, Yutao.) | Li, Yinqing (Li, Yinqing.) | Mitrovic, Ivona (Mitrovic, Ivona.) | Taylor, Stephen (Taylor, Stephen.) | Chalker, Paul (Chalker, Paul.) | Yang, Li (Yang, Li.) | Zhao, Cezhou (Zhao, Cezhou.)

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Abstract:

In this study, multi-walled carbon nanotubes/Cu nanowires-coated on the copper foil used as a three-dimensional porous current collector for Si electrode has been developed to tackle the problems of silicon-based lithium-ion batteries. The highly conductive Cu nanowires cooperated with robust multi-walled carbon nanotubes not only improve the inferior electric conductivity of the Si anode but also strengthen the total frame stability. Furthermore, the three-dimensional structure creates numerous voids on the surface of Cu foils. Such porous structure of the modified current collector offers the flexible volume expansion during lithiation/delithiation process. Meanwhile, the core-shell structure of multi-walled carbon nanotubes/Si and Cu nanowires/Si minimizes the deformation strain and greatly improves the long-term cycling performance in a real battery. As a result, a high specific capacity of 1845 mAh g−1 in a half cell at a current density of 3.5 A g−1 after 180 cycles with a capacity retention of 85.1% has been achieved without any conductive additives or binder. The demonstrated three-dimensional current collector coupled with Si anode might inspire new material development on high-performance of lithium-ion batteries. © 2019 Elsevier B.V.

Keyword:

Additives Anodes Electric current collectors Ions Lithium-ion batteries Multiwalled carbon nanotubes (MWCN) Nanotubes Nanowires Porous silicon Silicon

Author Community:

  • [ 1 ] [Zhao, Yinchao]Department of Electrical Engineering and Electronics, University of Liverpool, Liverpool; L69 3GJ, United Kingdom; Department of Electrical and Electronic Engineering, Xi'an Jiaotong-Liverpool University, Suzhou; 215123, China
  • [ 2 ] [Liu, Chenguang]Department of Electrical Engineering and Electronics, University of Liverpool, Liverpool; L69 3GJ, United Kingdom; Department of Electrical and Electronic Engineering, Xi'an Jiaotong-Liverpool University, Suzhou; 215123, China
  • [ 3 ] [Sun, Yi]Department of Electrical Engineering and Electronics, University of Liverpool, Liverpool; L69 3GJ, United Kingdom; Department of Electrical and Electronic Engineering, Xi'an Jiaotong-Liverpool University, Suzhou; 215123, China
  • [ 4 ] [Yi, Ruowei]Stephenson Institute for Renewable Energy, Department of Chemistry, University of Liverpool, Liverpool; L69 7ZD, United Kingdom; Department of Chemistry, Xi'an Jiaotong-Liverpool University, Suzhou; Jiangsu; 215123, China
  • [ 5 ] [Cai, Yutao]Department of Electrical Engineering and Electronics, University of Liverpool, Liverpool; L69 3GJ, United Kingdom; Department of Electrical and Electronic Engineering, Xi'an Jiaotong-Liverpool University, Suzhou; 215123, China
  • [ 6 ] [Li, Yinqing]Dongguan Hongde Battery Ltd.Co., Dongguan; 523649, China
  • [ 7 ] [Mitrovic, Ivona]Department of Electrical Engineering and Electronics, University of Liverpool, Liverpool; L69 3GJ, United Kingdom
  • [ 8 ] [Taylor, Stephen]Department of Electrical Engineering and Electronics, University of Liverpool, Liverpool; L69 3GJ, United Kingdom
  • [ 9 ] [Chalker, Paul]Centre for Advanced Materials, University of Liverpool, L69 3GH, United Kingdom
  • [ 10 ] [Yang, Li]Department of Chemistry, Xi'an Jiaotong-Liverpool University, Suzhou; Jiangsu; 215123, China
  • [ 11 ] [Zhao, Cezhou]Department of Electrical and Electronic Engineering, Xi'an Jiaotong-Liverpool University, Suzhou; 215123, China

Reprint Author's Address:

  • [Zhao, Cezhou]Department of Electrical and Electronic Engineering, Xi'an Jiaotong-Liverpool University, Suzhou; 215123, China;;

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Source :

Journal of Alloys and Compounds

ISSN: 0925-8388

Year: 2019

Volume: 803

Page: 505-513

4 . 6 5

JCR@2019

5 . 3 1 6

JCR@2020

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:131

JCR Journal Grade:2

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 16

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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