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Abstract:
The development of power system requires power capacitors to have higher energy density and smaller size, so to improve the breakdown strength (BDS) of polypropylene film, which is the dielectric material of capacitors, has drawn much attention. Nanocomposite is a promising way to achieve higher breakdown strength, but the poor compatibility of polymer matrix and nanoparticles has always been a problem. In the present study, we doped nano- ZrO2 into PP matrix, and together introduced maleic anhydride grafted polypropylene (PP-g-MAH) into the nanocomposite to form ternary system. Comparing with PP only doped with nano-ZrO2, the ternary system sample showed better dispersion of nanofillers. Besides, PP-g-MAH could help build stronger force between nanofillers and PP which was evidenced by the Fourier infrared test and differential scanning calorimetry test. Furthermore, we performed dynamic mechanical analysis test at different frequency and calculated the activation energy of molecular segment motions of the ternary samples, which was about 10% higher than the binary samples. As a result, the DC breakdown strength of ternary samples was about 9% higher than the sample only doped with nano-ZrO2, while the highest value of 387.7 kV/mm was obtained. © Springer Nature Switzerland AG 2020.
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ISSN: 1876-1100
Year: 2020
Volume: 599 LNEE
Page: 74-81
Language: English
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WoS CC Cited Count: 0
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 19
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