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Author:

Xiao Fengping (Xiao Fengping.) | Yang Xuming (Yang Xuming.) | Wang Hongkang (Wang Hongkang.) | Yu Denis Y W (Yu Denis Y W.) | Rogach Andrey L (Rogach Andrey L.)

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Abstract:

We introduce a hierarchical nanostructure of CoS2/N-doped carbon@MoS2 comprising two transition-metal sulfides CoS2 and MoS2, with enhanced sodium storage performance in sodium-ion batteries. A micron-sized Co metal-organic framework (MOF) is transformed into a CoS2/N-doped carbon composite, followed by a solvothermal growth of MoS2 nanosheets on the surface. The resulting composite material offers several specific advantages for sodium storage: (i) accelerated sodium-ion diffusion kinetics due to its heterogeneous interface; (ii) shortened ion diffusion path and exposed active sites for sodium storage due to its hierarchical nanosheet architecture; and (iii) homogeneous nitrogen doping of the MOF-derived carbon, which is beneficial for electronic conductivity. Due to these merits, this composite exhibits excellent electrochemical performance with a specific capacity of 596 mAh g-1 after 100 cycles at 0.1 A g-1 and 395 mAh g-1 at 5.0 A g-1.

Keyword:

composite hierarchical structure metal−organic frameworks sodium-ion battery transition-metal sulfides

Author Community:

  • [ 1 ] [Xiao Fengping]Department of Materials Science and Engineering, and Center for Functional Photonics (CFP), City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong Special Administrative Region, P. R. China
  • [ 2 ] [Yang Xuming]Department of Materials Science and Engineering, Southern University of Science and Technology, No. 1088 Xueyuan Road, Shenzhen 518055, Guangdong, P. R. China
  • [ 3 ] [Wang Hongkang]State Key Laboratory of Electrical Insulation and Power Equipment, Center of Nanomaterials for Renewable Energy (CNRE), School of Electrical Engineering, Xi'an Jiaotong University, Xi'an 710049, P. R. China
  • [ 4 ] [Yu Denis Y W]School of Energy and Environment, and Center of Super-Diamond and Advanced Films (COSDAF), City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong Special Administrative Region, P. R. China
  • [ 5 ] [Rogach Andrey L]Department of Materials Science and Engineering, and Center for Functional Photonics (CFP), City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong Special Administrative Region, P. R. China

Reprint Author's Address:

  • [Rogach, A.L.]Department of Materials Science and Engineering, 83 Tat Chee Avenue, Hong Kong;;[Rogach, A.L.]School of Energy and Environment, 83 Tat Chee Avenue, Hong Kong;;

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Source :

ACS applied materials & interfaces

ISSN: 1944-8252

Year: 2020

Issue: 49

Volume: 12

Page: 54644-54652

9 . 2 2 9

JCR@2020

9 . 2 2 9

JCR@2020

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:84

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 14

SCOPUS Cited Count: 59

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 9

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