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Abstract:
Lead-free dielectric capacitors for energy storage device have attracted increasing attention recently because of their high-power density and superior temperature stability. In this work, Nd-doped silver niobate (AgNbO3, abbreviated as AN) lead-free antiferroelectric ceramics were prepared by utilizing traditional solid state reaction method. A large energy storage density of 4.6 J/cm3 and an efficiency of 62.5% were simultaneously obtained in the 1% Nd-doped AN sample with an outstanding power density of 54.0 MW/cm3 and an ultrafast discharge speed (t0.9) of 59.2 ns. Additionally, the 1% Nd-doped AN ceramic demonstrates a good temperature stability from 25 degrees C to 130 degrees C. The excellent energy storage properties of the 1% Nd-doped ceramic is ascribed to the enhanced breakdown electric field induced by grain size engineering and the construction of phase structure via heterovalent substitution at the A-site of the lattice structure at room temperature. Our present work suggests that the 1% Nd-doped AN ceramic show promise for energy storage application in miniaturized mobile electronic devices and high-power equipment. (c) 2021 Elsevier B.V. All rights reserved.
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JOURNAL OF ALLOYS AND COMPOUNDS
ISSN: 0925-8388
Year: 2021
Volume: 877
5 . 3 1 6
JCR@2020
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:36
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 3
SCOPUS Cited Count: 50
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 9