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Author:

Shi, Peng (Shi, Peng.) | Wang, Xiangjian (Wang, Xiangjian.) | Lou, Xiaojie (Lou, Xiaojie.) (Scholars:娄晓杰) | Zhou, Chao (Zhou, Chao.) | Liu, Qida (Liu, Qida.) | He, Liqiang (He, Liqiang.) | Yang, Sen (Yang, Sen.) | Zhang, Xiaoxiao (Zhang, Xiaoxiao.)

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Abstract:

Lead-free dielectric capacitors for energy storage device have attracted increasing attention recently because of their high-power density and superior temperature stability. In this work, Nd-doped silver niobate (AgNbO3, abbreviated as AN) lead-free antiferroelectric ceramics were prepared by utilizing traditional solid state reaction method. A large energy storage density of 4.6 J/cm3 and an efficiency of 62.5% were simultaneously obtained in the 1% Nd-doped AN sample with an outstanding power density of 54.0 MW/cm3 and an ultrafast discharge speed (t0.9) of 59.2 ns. Additionally, the 1% Nd-doped AN ceramic demonstrates a good temperature stability from 25 degrees C to 130 degrees C. The excellent energy storage properties of the 1% Nd-doped ceramic is ascribed to the enhanced breakdown electric field induced by grain size engineering and the construction of phase structure via heterovalent substitution at the A-site of the lattice structure at room temperature. Our present work suggests that the 1% Nd-doped AN ceramic show promise for energy storage application in miniaturized mobile electronic devices and high-power equipment. (c) 2021 Elsevier B.V. All rights reserved.

Keyword:

Antiferroelectrics Energy storage Lead-free ceramics

Author Community:

  • [ 1 ] [Shi, Peng]Xi An Jiao Tong Univ, Sch Phys, MOE Key Lab Nonequilibrium Synth & Modulat Conden, Xian 710049, Shaanxi, Peoples R China
  • [ 2 ] [Zhou, Chao]Xi An Jiao Tong Univ, Sch Phys, MOE Key Lab Nonequilibrium Synth & Modulat Conden, Xian 710049, Shaanxi, Peoples R China
  • [ 3 ] [Yang, Sen]Xi An Jiao Tong Univ, Sch Phys, MOE Key Lab Nonequilibrium Synth & Modulat Conden, Xian 710049, Shaanxi, Peoples R China
  • [ 4 ] [Zhang, Xiaoxiao]Xi An Jiao Tong Univ, Sch Phys, MOE Key Lab Nonequilibrium Synth & Modulat Conden, Xian 710049, Shaanxi, Peoples R China
  • [ 5 ] [Shi, Peng]Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, State Key Lab Mech Behav Mat, Xian 710049, Shaanxi, Peoples R China
  • [ 6 ] [Lou, Xiaojie]Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, State Key Lab Mech Behav Mat, Xian 710049, Shaanxi, Peoples R China
  • [ 7 ] [He, Liqiang]Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, State Key Lab Mech Behav Mat, Xian 710049, Shaanxi, Peoples R China
  • [ 8 ] [Liu, Qida]Xi An Jiao Tong Univ, State Key Lab Strength & Vibrat Mech Struct, Xian 710049, Peoples R China
  • [ 9 ] [Wang, Xiangjian]Guangdong Univ Technol, Sch Mat & Energy, Guangzhou 510006, Peoples R China

Reprint Author's Address:

  • [Lou, Xiaojie]Frontier Institute of Science and Technology, and State Key Laboratory of Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an; Shaanxi; 710049, China;;

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Source :

JOURNAL OF ALLOYS AND COMPOUNDS

ISSN: 0925-8388

Year: 2021

Volume: 877

5 . 3 1 6

JCR@2020

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:36

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 3

SCOPUS Cited Count: 50

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 9

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