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Photothermal catalytic CO2 reduction has emerged as a promising approach to efficiently utilize solar energy and reduce greenhouse gas emissions. Designing novel catalyst with high activity and selectivity is essential and challenging for practical applications of photothermal CO2 reduction. Herein, we report that natural halloysite nanotubes-supported Ru nanoparticles can boost the photothermal catalytic activity and selectivity of CO2 methanation under continuous flow conditions. The photothermal catalytic performance of optimized catalyst is up to 1704 mmolCH4 gcat−1 h−1 with 93% CH4 selectivity and 68% CO2 conversion, outperforming any other Ru-based catalysts in photothermal CO2 reduction. Mechanistic studies show that the outstanding catalytic performance is mainly attributed to the unique mesoporous tubular structure, excellent ability of light-to-heat and interfacial interactions between the halloysite nanotubes and Ru. This method of utilizing natural minerals as support provides a facile avenue for rational design of abundant and low-cost catalysts for efficient photothermal catalytic CO2 reduction. © 2022 Elsevier B.V.
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Applied Catalysis B: Environmental
ISSN: 0926-3373
Year: 2023
Volume: 324
1 9 . 5 0 3
JCR@2020
ESI Discipline: CHEMISTRY;
Cited Count:
SCOPUS Cited Count: 42
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
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