The　volumetric　performance　of　supercapacitors　(SCs),　besides　the　gravimetric　performance,　is　attracting　an　increasing　attention　due　to　the　fast　development　of　electric　vehicles　and　smart　devices.　Here,　a　unique　design　of　symmetric　supercapacitor　material　is　reported　with　a　tight　face-to-face　architecture　by　applying　a　high　pressure　to　the　delaminated　Ti3C2　(d-Ti3C2)　films.　The　high　pressure　makes　the　d-Ti3C2　films　achieve　an　increased　density,　high　electron　conductivity,　good　wettability,　and　abundant　interconnected　mesopore　channels　to　promote　ion　transport　efficiently,　that　is,　more　cations　can　intercalate/deintercalate　in　the　charging-discharging　process.　As　a　result,　with　the　increase　of　the　applying　pressure,　the　d-Ti3C2　film　pressured　at　40　MPa　in　1　M　Li2SO4　exhibits　an　ultrahigh　capacitance　of　over　633　F　cm(-3),　outstanding　energy　density,　and　cyclic　stability.　Especially,　the　corresponding　SC　in　1　M　1-ethyl-3-methylimidazolium　tetrafluoroborate/acetonitrile　organic　electrolyte　shows　a　high　volumetric　energy　density　of　41　Wh　L-1,　which　is　the　highest　value　reported　for　the　SCs　based　on　MXene　materials　in　organic　electrolytes.　The　outstanding　volumetric　electrochemical　performance　and　thermal　stability　of　the　SCs　based　on　the　ultracompact　d-Ti3C2　film　demonstrate　their　promising　potential　as　forceful　power　sources　for　small　electronic　devices.