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The surface of NiTi alloy was roughened by NaOH-HCl treatment, and the Ta-containing TiO2 films were coated on the pretreated NiTi alloy by the sol-gel method. Thermal analyses indicate that the evaporation temperature of the organics decreases with the addition of tantalum ethoxide in the TiO2 sol, but the crystallization temperature of anatase increases. The NaOH-HCl pretreatment improves the film integrity, but cracks still form in the films at high Ta contents (a parts per thousand yen20 %, molar ratio) owing to the increasing film thickness. X-ray diffraction (XRD) confirms that the addition of Ta suppresses the crystallization of anatase. X-ray photoelectron spectroscopy (XPS) reveals that Ta exists as Ta2O5 in the film. With the increase of Ta content, the hydrophilic conversion of the films under UV illumination is impeded, but their corrosion resistance in 0.9 % NaCl solution increases, tested by the potentiodynamic polarization. The coating samples have acceptable hemolysis ratios for biomaterials (< 5). The introduction of Ta improves the anti-aggregating function of the TiO2 film in the platelet adhesion test.
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RARE METALS
ISSN: 1001-0521
Year: 2014
Issue: 1
Volume: 33
Page: 21-27
1 . 0 0 9
JCR@2014
4 . 0 0 3
JCR@2020
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:291
JCR Journal Grade:3
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 13
SCOPUS Cited Count: 20
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4