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Abstract:
Ag-containing TiO2 films (Ag/Ti=3.3, 9.1 at%) were sol-gel coated on NiTi alloy that had been surface roughened by the NaOH-HCl treatment for antibacterial application. Thermal analyses of the dried gels reveal that the addition of 9.1 at% Ag lowers the anatase-rutile transformation temperature from 618 to 586 degrees C. Morphological observation shows that surface roughening and silver addition improve structural integrity of the TiO2 films. X-ray diffraction reveals that the addition of Ag does not obviously change crystallinity of the anatase films. X-ray photoelectron spectroscopy results indicate metallic nature of Ag in the film and complete coverage of the films on the roughened alloy substrate. Microindentation test exhibits that the Ag-TiO2 film on the roughened substrate has higher cohesive strength than that on the polished substrate. The potentiodynamic polarization test in a Ca-free Hank's balanced salt solution demonstrates good protection of the TiO2 and Ag-TiO2 films for the alloy substrate. Ultraviolet light illumination for 3 h can increase surface hydrophilicity of the coated NiTi samples by reducing contact angles from > 65 degrees to <20 degrees. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
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CERAMICS INTERNATIONAL
ISSN: 0272-8842
Year: 2014
Issue: 8
Volume: 40
Page: 12423-12429
2 . 6 0 5
JCR@2014
4 . 5 2 7
JCR@2020
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:291
JCR Journal Grade:2
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 19
SCOPUS Cited Count: 21
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 3
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