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Author:

Li, Naixu (Li, Naixu.) | Tu, Ying (Tu, Ying.) | Wang, Ke (Wang, Ke.) | Huang, Dongxiao (Huang, Dongxiao.) | Shen, Quanhao (Shen, Quanhao.) | Chen, Wenshuai (Chen, Wenshuai.) | Zhou, Jiancheng (Zhou, Jiancheng.) | Ma, Quanhong (Ma, Quanhong.) | Liu, Maochang (Liu, Maochang.)

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Abstract:

Aiming at the bottleneck of thermodynamics, kinetics and reaction systems in photothermal catalytic CO2 reduction conversion, a three-field coupling method based on the efficient utilization of solar energy and the application of a photo-thermal-magnetic three-field was proposed to achieve efficient and highly selective CO2 conversion. The composite monolithic catalyst with three field response functions and multiple active reaction interfaces was prepared by using photoactive copper supported by nickel foam. The effect of an external alternating magnetic field on photocatalytic CO2 reduction was studied using a range between 0.005 and 0.1 wt% Cu/Cu2O/Ni(OH)(2)/NF as catalysts. The results showed that 0.01 wt% Cu/Cu2O/Ni(OH)(2)/NF exhibited the best catalytic activity and CH4 selectivity under alternating magnetic field enhanced photocatalysis. The main products were CO (6.76 mu mol g(-1)) and CH4 (167 mu mol g(-1)). The selectivity of CH4 was 96.1%. The yields of CH4 using this method were 11 and 6 times higher than the yields obtained with photocatalysis (14.58 mu mol g(-1)) and magnetic-thermal catalysis (26.75 mu mol g(-1)), respectively. According to the analysis of temperature measurements and electrochemical measurements, the surface temperature of the three-field coupled catalyst reaches about 230 degrees C. Applying an alternating magnetic field can effectively reduce the recombination of photogenerated electron holes. Alternating magnetic field enhanced photocatalytic CO2 reduction conversion provides a new and promising method for the efficient conversion and utilization of solar energy.

Keyword:

Alternating magnetic field CO2 reduction Nickel foam Photothermal catalysis

Author Community:

  • [ 1 ] [Li, Naixu]Southeast Univ, Sch Chem & Chem Engn, 2 Dongnandaxue Rd, Nanjing 211189, Peoples R China
  • [ 2 ] [Tu, Ying]Southeast Univ, Sch Chem & Chem Engn, 2 Dongnandaxue Rd, Nanjing 211189, Peoples R China
  • [ 3 ] [Wang, Ke]Southeast Univ, Sch Chem & Chem Engn, 2 Dongnandaxue Rd, Nanjing 211189, Peoples R China
  • [ 4 ] [Huang, Dongxiao]Southeast Univ, Sch Chem & Chem Engn, 2 Dongnandaxue Rd, Nanjing 211189, Peoples R China
  • [ 5 ] [Shen, Quanhao]Southeast Univ, Sch Chem & Chem Engn, 2 Dongnandaxue Rd, Nanjing 211189, Peoples R China
  • [ 6 ] [Zhou, Jiancheng]Southeast Univ, Sch Chem & Chem Engn, 2 Dongnandaxue Rd, Nanjing 211189, Peoples R China
  • [ 7 ] [Ma, Quanhong]Southeast Univ, Sch Chem & Chem Engn, 2 Dongnandaxue Rd, Nanjing 211189, Peoples R China
  • [ 8 ] [Liu, Maochang]Xi An Jiao Tong Univ, Int Res Ctr Renewable Energy, State Key Lab Multiphase Flow Power Engn, 28 Xianning West Rd, Xian 710049, Shaanxi, Peoples R China
  • [ 9 ] [Chen, Wenshuai]Northeast Forestry Univ, Key Lab Biobased Mat Sci & Technol, Minist Educ, 26 Hexing Rd, Harbin 150040, Peoples R China
  • [ 10 ] [Li, Naixu]Jiangsu Key Lab Biomass Energy & Mat, 16 Suojin Wucun, Nanjing 210042, Peoples R China

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Source :

CHEMICAL ENGINEERING JOURNAL

ISSN: 1385-8947

Year: 2021

Volume: 421

1 3 . 2 7 3

JCR@2020

ESI Discipline: ENGINEERING;

ESI HC Threshold:30

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count: 23

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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