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Abstract:
In this study, the phase diagram of the NaCl+RbCl binary system was measured using differential scanning calorimetry, and the measured molar percentages of the binary mixture RbCl ranged from 12 to 97 mol%, updating and extending the experimental data for this binary system. The liquid phase of this system was thermodynamically modeled using a modified quasichemical model, and a computer optimization program for evaluation of the experimental data on phase equilibria and other thermodynamic data was developed based on this model. All thermodynamic models of the NaCl+RbCl binary system were constructed; calculations of the phase diagram, enthalpy of mixing, and activity coefficient of NaCl of the NaCl+RbCl binary system were completed using the obtained model parameters; and the calculated eutectic point positions were x(RbCl) = 0.567 and 550.2 degrees C. The calculated results were able to reproduce the various types of experimental data well, and the thermodynamic self-consistency between different types of experimental data was demonstrated.
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MATERIALS
Year: 2022
Issue: 18
Volume: 15
3 . 6 2 3
JCR@2020
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:7
Cited Count:
SCOPUS Cited Count: 1
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 9
Affiliated Colleges: