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Author:

Kang, Zhangyang (Kang, Zhangyang.) | He, Maogang (He, Maogang.) | Lu, Guangxuan (Lu, Guangxuan.)

Indexed by:

SCIE Scopus Web of Science

Abstract:

In this study, the phase diagram of the NaCl+RbCl binary system was measured using differential scanning calorimetry, and the measured molar percentages of the binary mixture RbCl ranged from 12 to 97 mol%, updating and extending the experimental data for this binary system. The liquid phase of this system was thermodynamically modeled using a modified quasichemical model, and a computer optimization program for evaluation of the experimental data on phase equilibria and other thermodynamic data was developed based on this model. All thermodynamic models of the NaCl+RbCl binary system were constructed; calculations of the phase diagram, enthalpy of mixing, and activity coefficient of NaCl of the NaCl+RbCl binary system were completed using the obtained model parameters; and the calculated eutectic point positions were x(RbCl) = 0.567 and 550.2 degrees C. The calculated results were able to reproduce the various types of experimental data well, and the thermodynamic self-consistency between different types of experimental data was demonstrated.

Keyword:

activity coefficient differential scanning calorimetry modified quasichemical model phase diagram phase equilibria thermodynamics

Author Community:

  • [ 1 ] [Kang, Zhangyang]North China Univ Water Resources & Elect Power, Sch Environm & Municipal Engn, Zhengzhou 450046, Peoples R China
  • [ 2 ] [He, Maogang]Xi An Jiao Tong Univ, Sch Energy & Power Engn, Minist Educ, Key Lab Thermofluid Sci & Engn, Xian 710049, Peoples R China
  • [ 3 ] [Lu, Guangxuan]Western Met Mat Co Ltd, Xian 710201, Peoples R China

Reprint Author's Address:

  • [Kang, Z.]School of Environmental and Municipal Engineering, China;;

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Source :

MATERIALS

Year: 2022

Issue: 18

Volume: 15

3 . 6 2 3

JCR@2020

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:7

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 9

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