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Abstract:
Differential scanning calorimetry analysis of the various compositions in the (LiCl+CsCl) and (LiCl+KCI+CsCl) systems have been performed, and the composition of 55.5:19.5:25 mol% and 263 C were considered as a eutectic point in the (LiCI+KCI+CsCI) ternary system. A careful evaluation and optimization of our measured phase diagram data and all the other available experimental data for the (LiCI+CsCI) and (LiCI+KCI+CsCI) systems were performed to obtain optimized model parameters for all solid and liquid phases. A thermodynamic data set has been formed and may be used to calculate phase equilibrium and all thermodynamic properties in the (LiCl+KCI+CsCl) ternary system. A density model based on the Modified Quasichemical Model has been employed to evaluate all available density data of the (LiCl+KCI), (KCI+CsCl), (LiCl+CsCl) and (LiCl+KCI+CsCl) melts, and optimized parameters for the density model generated a useful database that can be used to complete a prediction for the density of all liquid phases. (C) 2016 Elsevier Ltd. All rights reserved.
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CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
ISSN: 0364-5916
Year: 2016
Volume: 55
Page: 208-218
1 . 6
JCR@2016
2 . 0 1 7
JCR@2020
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:239
JCR Journal Grade:2
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 4
SCOPUS Cited Count: 5
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 5
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