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Author:

Kang, Zhangyang (Kang, Zhangyang.) | He, Maogang (He, Maogang.) (Scholars:何茂刚) | Lu, Guangxuan (Lu, Guangxuan.) | Zhang, Ying (Zhang, Ying.)

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SCIE EI Scopus

Abstract:

Differential scanning calorimetry analysis of the various compositions in the (LiCl+CsCl) and (LiCl+KCI+CsCl) systems have been performed, and the composition of 55.5:19.5:25 mol% and 263 C were considered as a eutectic point in the (LiCI+KCI+CsCI) ternary system. A careful evaluation and optimization of our measured phase diagram data and all the other available experimental data for the (LiCI+CsCI) and (LiCI+KCI+CsCI) systems were performed to obtain optimized model parameters for all solid and liquid phases. A thermodynamic data set has been formed and may be used to calculate phase equilibrium and all thermodynamic properties in the (LiCl+KCI+CsCl) ternary system. A density model based on the Modified Quasichemical Model has been employed to evaluate all available density data of the (LiCl+KCI), (KCI+CsCl), (LiCl+CsCl) and (LiCl+KCI+CsCl) melts, and optimized parameters for the density model generated a useful database that can be used to complete a prediction for the density of all liquid phases. (C) 2016 Elsevier Ltd. All rights reserved.

Keyword:

Density Differential scanning calorimetry Modified Quasichemical Model Phase diagram Thermodynamic evaluation

Author Community:

  • [ 1 ] [Kang, Zhangyang; He, Maogang; Lu, Guangxuan; Zhang, Ying] Xi An Jiao Tong Univ, Sch Energy & Power Engn, Minist Educ, Key Lab Thermofluid Sci & Engn, Xian 710049, Peoples R China
  • [ 2 ] [Kang, Zhangyang]Xi An Jiao Tong Univ, Sch Energy & Power Engn, Minist Educ, Key Lab Thermofluid Sci & Engn, Xian 710049, Peoples R China
  • [ 3 ] [He, Maogang]Xi An Jiao Tong Univ, Sch Energy & Power Engn, Minist Educ, Key Lab Thermofluid Sci & Engn, Xian 710049, Peoples R China
  • [ 4 ] [Lu, Guangxuan]Xi An Jiao Tong Univ, Sch Energy & Power Engn, Minist Educ, Key Lab Thermofluid Sci & Engn, Xian 710049, Peoples R China
  • [ 5 ] [Zhang, Ying]Xi An Jiao Tong Univ, Sch Energy & Power Engn, Minist Educ, Key Lab Thermofluid Sci & Engn, Xian 710049, Peoples R China

Reprint Author's Address:

  • 何茂刚

    Xi An Jiao Tong Univ, Sch Energy & Power Engn, Minist Educ, Key Lab Thermofluid Sci & Engn, Xian 710049, Peoples R China.

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Source :

CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY

ISSN: 0364-5916

Year: 2016

Volume: 55

Page: 208-218

1 . 6

JCR@2016

2 . 0 1 7

JCR@2020

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:239

JCR Journal Grade:2

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 4

SCOPUS Cited Count: 5

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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